The The Amazing Spider-Man 2 costars are captivating in real life, too, with Emma radiating beauty in color-blocked Thakoon.
The couple are honoring the Hollywood code of looking postively dashing when it comes to all red carpets. Jessica looks like a life-size Oscar in gold Diane Von Furstenberg.
The Topshop-clad supermodel and her Topman-wearing hip-hopper beau are still going strong.
The foul-mouthed comedian, who will be guest-starring on her beau's Showtime drama Masters of Sex, has never looked more glam, wears Zac Posen for their red carpet debut as a couple.
The New York Knicks star wears a top hat and his wife is just tops in Cushnie et Ochs.
These two are always golden: Kruger is picture-perfect in Jason Wu for Hugo Boss.
The Homeland star looks like she hails from Happy Ever After in Oscar de la Renta.
It should be a rule that Hugh just wear a tuxedo—by Tom Ford like tonight or even off the rack—to everything. "Headed out for an awesome night with my beautiful wife @Deborra_lee #TasteofSpring #METBALL," the all-around handsome human being tweeted earlier.
All of him and all of her look super-hot in Ralph Lauren.
Queen Bey channels 1920s glam from head to toe in Givenchy, though the 20s would have Roared a lot more if more gals had worn those sorts of necklines.
Looks like the football star got his hair under control in time to stun on the red carpet with his Balenciaga-wearing wife.
The engaged duo look positively dashing, not least because of the groom-to-be's cane. He's in Ralph Lauren Purple Label, while the lady stuns in Giambattista Valli.
Kim's flashing a little Angelina leg in Lanvin after recovering from a wardrobe malfunction while en route to the main event.
Well, these two clean up nicely.
Once again, these two are just everything, with Posh in a gown from her own label and her hubby in a Ralph Lauren Black Label tux.
The actress channels old-Hollywood glam in Gucci. And, not to mention, it's a real, live red carpet shot of the super-private, Connecticut-based couple!
So the longtime couple are wearing...these outfits, by Thom Browne.
The Breaking Bad star takes a night off from playing LBJ on Broadway and looks awfully good alongside his wife of 25 years.
The pregnant actress,wearing a dramatic strapless gown by Tommy Hilfiger, has the most glam bump on the block.
The actor, looking dapper in white tie, risks being overshadowed by his girlfriend's appliqués-gown-crazy gown.
If neither is wearing Ralph Lauren, then we're stumped.
NEXT GALLERY: 2014 Met Gala Arrivals